Fe+2HCl->FeCl₂+H₂

x---2x-----------x

Mg+2HCl->MgCl₂+H₂

y------2y-----------y

Ta có :

\(\left\{{}\begin{matrix}56x+24y=24\\x+y=\dfrac{13,44}{22,4}\end{matrix}\right.\)

=>x=0,3 mol, y=0,3 mol

=>%m Fe=\(\dfrac{0,3.56}{24}.100\)=70%

=>%m Mg=100-70=30%

=>VHCl=\(\dfrac{0,3.2+0,3.2}{2}\)=0,6l=600ml

b)

 XCl₂+2AgNO₃->2AgCl+X(NO₃)₂

0,6--------------------1,2mol

=>m AgCl=1,2.143,5=172,2g

PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{Fe}=n_{FeCl_2}=n_{H_2}=0,2\left(mol\right)\\n_{HCl}=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,2\cdot56=11,2\left(g\right)\\m_{FeCl_2}=0,2\cdot127=25,4\left(g\right)\\m_{ddHCl}=\dfrac{0,4\cdot36,5}{10\%}=146\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{Fe}+m_{ddHCl}-m_{H_2}=156,8\left(g\right)\) \(\Rightarrow C\%_{FeCl_2}=\dfrac{25,4}{156,8}\cdot100\%\approx16,2\%\)

Gọi x, y tương ứng là số mol Mg và MgO: 24x + 40y = 8,8.

x + y = nMgCl2 = 28,5/95 = 0,3

Giải hệ thu được: x = 0,2; y = 0,1.

a) %Mg = 24.0,2/8,8 = 54,54%; %MgO = 100 - 54,54 = 45,46%

b) nHCl = 2(x+y) = 0,6 mol; mdd =36,5.0,6.100/14,6 = 150 gam.

c) mdd sau p.ư = 8,8 + 150 - mH2 = 158,8 - 2.0,2 = 158,4 gam.

%MgCl2 = 28,5/158,4 = 17,99%

Theo gt ta có: $n_{Al}=0,1(mol)$

a, $2Al+6HCl\rightarrow 2AlCl_3+3H_2$

b, $\Rightarrow n_{H_2}=0,15(mol)\Rightarrow V_{H_2}=3,36(l)$

c, Ta có: $n_{HCl}=0,3(mol)\Rightarrow m_{HCl}=10,95(g)\Rightarrow \%m_{ddHCl}=219(g)$

d, Bảo toàn khối lượng ta có: $m_{dd}=221,4(g)$

$\Rightarrow \%C_{AlCl_3}=6,02\%$

\(n_{Al} = \dfrac{10,8}{27} = 0,4(mol)\\ 2Al + 6HCl \to 2AlCl_3 + 3H_2\\ n_{AlCl_3} = n_{Al} = 0,4(mol)\\ m_{AlCl_3} = 0,4.133,5 = 53,4(gam)\\ n_{HCl} =3 n_{Al} = 1,2(mol)\\ C\%_{HCl}= \dfrac{1,2.36,5}{200}.100\% = 21,9\%\)

\(a)n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=n_{H_2}=n_{ZnCl_2}=0,1mol\\ m_{Zn}=0,1.65=6,5g\\ m_{Cu}=9,7-6,5=3,2g\\ b)C_{\%ZnCl_2}=\dfrac{0,1.136}{6,5+120-0,1.2}\cdot100=10,77\%\)

PTHH: \(K_2SO_3+2HCl\rightarrow2KCl+H_2O+SO_2\uparrow\)

a+b+c) Ta có: \(n_{SO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{KCl}=0,5\left(mol\right)=n_{HCl}\\n_{K_2SO_3}=0,25\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{K_2SO_3}=0,25\cdot158=39,5\left(g\right)=a\\m_{KCl}=0,5\cdot74,5=37,25\left(g\right)\\m_{ddHCl}=\dfrac{0,5\cdot36,5}{10,95\%}\approx166,67\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{SO_2}=0,25\cdot64=16\left(g\right)\)

\(\Rightarrow m_{dd}=m_{K_2SO_3}+m_{ddHCl}-m_{SO_2}=190,17\left(g\right)\) \(\Rightarrow C\%_{KCl}=\dfrac{37,25}{190,17}\cdot100\%\approx19,59\%\)

d) PTHH: \(NaOH+HCl\rightarrow NaCl+H_2O\)

Theo PTHH: \(n_{NaOH}=n_{HCl}=0,5\left(mol\right)\) \(\Rightarrow V_{NaOH}=\dfrac{0,5}{0,5}=1\left(l\right)\)